单缸摩托车发动机中低速性能优化

目的 解决某单缸摩托车发动机台架测试时中低速扭矩线性度差的问题.方法 基于CFD数值分析方法,运用热力学仿真分析软件GT-Power对发动机进行建模和标定,然后对原方案发动机进行摸底分析,最后通过优化配气机构和进排气系统来实现改善中低速性能的目标.结果 优化后的发动机台架测试结果中,发动机中低速扭矩线性度改善,动力性和经济性及排放都达到项目预期目标,峰值功率达到16 kW(9500 r/min),峰值扭矩达到18.6 N·m(7000 r/min),最低比油耗为183 g/(kW·h),CO、THC、NOx排放量分别为840、83、54 mg/km.配气机构运动学动力学性能与可靠性提升,进排气凸轮丰满系数分别达到5.14、5.15.结论 原方案中低速扭矩线性度差的原因为此转速段充气效率较低.优化凸轮型线、空滤器、消声器、排气管道参数能更好地利用进排气管道谐振效应来提升发动机中低速动力性能.     

以浮游生物为指示生物的苏州河生态安全评价

采用斜生栅藻,羊角月牙藻和大水蚤对苏州河主要几种重金属以及不同河段河水及底泥进行了生态影响实验,得到了以大水蚤EC50为指标的苏州河主要几种重金属生态安全阈值。同时结果还表明,与郊区黄渡段相比,苏州河市区河段河水对供试浮游生物呈现了一定的抑制作用,某些点位的生态影响甚至达到统计学显著性水平。黑泥层底泥抑制作用大于浮泥层底泥。因此,尽管苏州河经过二期整治后,水环境质量的景观指标有明显改善,但市区段河水和底泥对生物定居仍有一定的抑制作用,对苏州河生态安全构成一定的影响。     

Synergistic effect of F and triggered oxygen vacancies over F-TiO2 on enhancing NO ozonation

Oxidation-absorption technology is a key step for NO_x removal from low-temperature gas. Under the condition of low O₃ concentration (O₃/NO molar ratio = 0.6), F-TiO₂ (F-TiO₂), which is cheap and environmentally friendly, has been prepared as ozonation catalysts for NO oxidation. Catalytic activity tests performed at 120°C showed that the NO oxidation efficiency of F-TiO₂ samples was higher than that of TiO₂ (about 43.7%), and the NO oxidation efficiency of F-TiO₂-0.15 was the highest, which was 65.3%. Combined with physicochemical characteristics of catalysts and the analysis of active species, it was found that there was a synergistic effect between F sites and oxygen vacancies on F-TiO₂, which could accelerate the transformation of monomolecular O₃ into multi-molecule singlet oxygen (¹O₂), thus promoting the selective oxidation of NO to NO₂. The oxidation reaction of NO on F-TiO₂-0.15 follows the Eley-Rideal mechanism, that is, gaseous NO reacts with adsorbed O₃ and finally form NO₂.     

取代苯类化合物的二维息定量结构-活性相关研究

为了预测非反应性麻醉型化合物对发光菌的发光半抑制浓度,评价该类化合物的毒性效应,采用独特的二维HQSAR分析方法,根据分子碎片的类型,将分子结构转变成具有特征的分子指纹,并用数字进行标记。这些标记出的数字作为QSAR的描述符,经过偏最小二乘法计算,建立起化合物结构与生物毒性之间的相关关系,由此所获得的HQSAR预测值与实测值之间也存在较好的相关性,即-1g_(pre)EC_(50)=0.311 0.929(-1g_(exp)EC_(50))(n=13,r=0.964)。这一模型的预测效果明显优于传统的二维QSAR模型,其结果可以为定量评估同类化合物的生物毒性提供可靠依据。     

Interfacial effects of suspended particles on biodegradation of N (2,4 dimethyl phenyl) N'' methylformamidine hydrochloride and dibutyl phthalate in waters

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Sex-dependent obesogenic effect of tetracycline on Drosophila melanogaster deteriorated by dysrhythmia

Antibiotics have been identified as obesogens contributing to the prevalence of obesity. Moreover, their environmental toxicity shows sex dependence, which might also explain the sex-dependent obesity observed. Yet, the direct evidence for such a connection and the underlying mechanisms remain to be explored. In this study, the effects of tetracycline, which is a representative antibiotic found in both environmental and food samples, on Drosophila melanogaster were studied with consideration of both sex and circadian rhythms (represented by the eclosion rhythm). Results showed that in morning-eclosed adults, tetracycline significantly stimulated the body weight of females (AM females) at 0.1, 1.0, 10.0 and 100.0 µg/L, while tetracycline only stimulated the body weight of males (AM males) at 1.0 µg/L. In the afternoon-eclosed adults, tetracycline significantly stimulated the body weight of females (PM females) at 0.1, 1.0 and 100.0 µg/L, while it showed more significant stimulation in males (PM males) at all concentrations. Notably, the stimulation levels were the greatest in PM males among all the adults. The results showed the clear sex dependence of the obesogenic effects, which was diminished by dysrhythmia. Further biochemical assays and clustering analysis suggested that the sex- and rhythm-dependent obesogenic effects resulted from the bias toward lipogenesis against lipolysis. Moreover, they were closely related to the preference for the energy storage forms of lactate and glucose and also to the presence of excessive insulin, with the involvement of glucolipid metabolism. Such relationships indicated potential bridges between the obesogenic effects of pollutants and other diseases, e.g., cancer and diabetes.     

滞洪型平原水库蓄水对水环境影响分析及其协同调控研究

本文通过滞洪型水库运行机理的介绍,以石佛寺水库为例,提出利用地表水和地下水协同调控解决蓄水带来的环境负效应,通过建立库区水环境统一模型,利用数值模拟方法分析预测水库蓄水对环境的影响,并对解决水库蓄水产生的环境负效应进行方案的优化选择,最终提出地表水库蓄水和地下水库供水的最优方案.     

PO4^3-和柠檬酸对稀土元素在小麦体内积累和分异的影响

基于营养液培养,添加外源稀土和ICP-MS分析技术,研究了无机配体PO43-(Pi)及有机配体柠檬酸(Cit)对小麦器官中稀土元素积累和分异的影响.结果表明,不同Pi水平对小麦根中的稀土总含量(∑REE)影响较小,但显著降低叶中∑REE含量;而不同Cit水平对小麦根、叶中∑REE含量都有明显降低作用.对照植物(无Pi、Cit添加)中,稀土元素在小麦根中具有中稀土(MREE)富集及M-型四重效应分布特征,叶中有重稀土(HREE)富集及W-型四重效应分布特征.不同Pi处理对四重效应无明显作用,但进一步加强HREE在小麦叶片中的富集.添加柠檬酸使对照植物根和叶中的分异有逐渐减弱的趋势,在高浓度处理时(Cit≥150μmol.L-1),小麦根和叶中出现轻稀土(LREE)富集.     

2000年以来黄河流域土地市场化时空格局演变及驱动因素

基于土地市场交易结构的视角,测算2000-2016年黄河流域104个地级以上城市一级土地市场化程度,综合利用Global Moran's I、G^*_i指数空间统计模型对其时空格局演变特征进行分析,运用灰色关联度分析模型探究土地市场化时空格局演变的主要驱动因素。研究发现：2000-2016年,黄河流域土地市场化水平表现出先持续上升后不断下降的阶段性变化特征,呈现了“东高西低”的空间分异格局。黄河流域土地市场化水平整体具有显著的空间自相关性,土地市场化热点区域以下游主要城市为核心,经历了先加速蔓延、后缓步收缩的时空演进历程。黄河流域土地市场化水平的时空格局演变主要由经济发展水平、产业结构升级、固定资产投资、政府财政收支比、外商直接投资以及区位条件等因素共同驱动,但受我国社会经济发展的阶段性影响,各因素在不同年份的影响程度存在显著的差异性。     

荧光光谱法研究丙酮与牛血清白蛋白的相互作用特征

在模拟动物体生理条件和不同温度下,用荧光光谱、三维荧光光谱、同步荧光光谱、紫外可见吸收光谱法等研究了丙酮(ACET)与牛血清白蛋白(BSA)的相互作用,证实了丙酮有很强的猝灭BSA荧光强度的能力.分别用Sterr-Volmer方程、Lineweaver-Burk双倒数方程和热力学方程等分析和处理试验数据,得到了它们相互作用的生成常数KLV(平均值为7.073×106L·mol-1)、热力学参数(△Hθ、△Gθ和△Sθ的平均值分别为-3.982kJ·mol-1、-26.51 kJ·mol-1和73.31J·K-1)和结合位点数(平均值为1.266)等.这为研究ACET对BSA构象的影响、ACET的毒理效应和生物学效应提供了重要信息.